Brahmia Ahmed, Meddeb Zina, Experimental Study by the Plan Composite Centered Method, Modeling and Optimization of Hydrogen Production by Alkaline Electrolysis, Journal of New Developments in Chemistry, Volume 4, Issue 1, 2023, Pages 1-17, ISSN 2377-2549, https://doi.org/10.14302/issn.2377-2549.jndc-23-4494.
(https://oap-researcharticles.org/jndc/article/1955)
Abstract: A planned experimental study on the production of green hydrogen by alkaline electrolysis is carried out by the Plan Composite Centered (PCC) method. The parameters studied are the concentration of the electrolyte, the distance between electrodes, the height of the electrodes, the total supply voltage of the electrolyser, temperature, and the electrolyte type. The results show that the effect of concentration, height, voltage and temperature are positive. However, the effect of the distance between the electrodes is negative. Electrolysis with potassium hydroxide (KOH) is more efficient than with sodium hydroxide (NaOH). The second-order interactions are weak, except for the voltage-temperature interaction which is significant. The results of the experimental study conducted in this work are in agreement with previous studies. Two a polynomial modeling (with KOH and with NaOH) suitable for predicting the flow of hydrogen produced are presented. Three optimizations of ascending constraints on the operating parameters to have a maximum hydrogen production and with a minimum of electrical energy and a minimum of concentration consumed are carried out.
Keywords: Green hydrogen; alkaline electrolysis; plan of experiments; modelling; optimization.